Class

A class consists of elements of a group that are conjugate to one another. Two elements  are conjugate to each other if , where . If  is conjugate to , then  is conjugate to , as

where  (note that  according to the inverse property of a group). The identity element  is a class by itself since .

If the elements of  are represented by matrices,  is called a similarity transformation. Furthermore, if  and  are conjugate to each other, and  and  are conjugate to each other, then  and  are conjugate to each other. This is because  and  and therefore, , where .

Question

Show that the symmetry operators ,  and  of the point group belong to the same class.

Answer

With reference to the multiplication table,

we have

Similarly, . Since  and  are conjugate to each other, and and  are conjugate to each other, then  and  are conjugate to each other. Therefore,  form a class. Using the same logic, we find that  and  form another class.

 

All elements of the same class in a group  have the same order, which is defined as the smallest value of  such that , where . This is because if is conjugate to , we have

The above equation of  is valid if and only if . This means that the smallest value of  in and in  must be the same. Therefore, elements  and  of the same class in a group have the same order and is denoted by .

Question

Verify that the symmetry operators , and of the point group have the same order of 2.

Answer

It is clear that when the reflection operator  acts on a shape twice, it sends the shape into itself. The same goes for  and . Hence, .

 

As mentioned in an earlier article, the similarity transformation of a matrix  to a matrix  leaves the trace of , which is defined as , invariant. This implies that elements of the same class in a group have the same trace.

 

Next article: Group representations
Previous article: Crystallographic point groups
Content page of group theory
Content page of advanced chemistry
Main content page

Leave a Reply

Your email address will not be published. Required fields are marked *