pH indicators: overview

A pH indicator is usually a large, weak organic acid that is soluble in water or alcohol.

\begin{matrix} HIn(aq)\\colourA \end{matrix}\rightleftharpoons H^+(aq)+\begin{matrix} In^-(aq)\\colourB \end{matrix}

The acid HIn absorbs a certain range of wavelengths of visible light and reflects the rest (complementary range of wavelengths) into our eyes, which perceive the complementary wavelengths as Colour A. The conjugate base In absorbs a different range of wavelengths of visible light and reflects a dissimilar complementary range into our eyes, which perceive it as Colour B.

The acid may be a neutral or charged molecule, for example, the acid form of the indicator bromocresol green is monoanionic (yellow), while its conjugate base is dianionic (blue).

 

 

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