Subatomic particle mass, encompassing the masses of protons, neutrons, and electrons, is fundamental to understanding the structure of matter and the behavior of atoms in chemical reactions.
The mass of a proton can be determined via mass spectrometry in the same way as described in a previous article. The mass of a neutron, mn, however, cannot be measured via mass spectrometry as it lacks a charge.
Particle |
Symbol | Relative mass, u |
Inertia mass, kg |
Proton |
p or H+ | 1.007276466879 |
1.672621898 x 10-27 |
Neutron |
n | 1.00866491588 |
1.674927471 x 10-27 |
Electron |
e | 5.485799090 x 10-4 |
9.10938356 x 10-31 |
From eq9 of the article on mass defect, we have:
Hence, the mass of a neutron can be calculated by subtracting the mass of a proton, mp, from the mass of a deuterium nucleus (both obtained from mass spectrometry), and adding the mass defect of deuterium, mdefect, which can be measured using X-ray diffraction for the gamma ray released when a neutron captures a proton:
The charge-to-mass ratio of an electron was first estimated by J. J. Thomson, an English physicist, in 1896 using cathode rays. Combining this value with the quantity of charge of a single electron from Robert Millikan’s oil drop experiment, an estimated mass of an electron could be determined. A more precise value, the rest mass of an electron, me, is however calculated from the Rydberg constant, where