Orthogonality of the associated Laguerre polynomials

The orthogonality of the associated Laguerre polynomials states that the integral of the product of two distinct associated Laguerre polynomials over a specified interval is zero.

It is defined mathematically as:

where is known as a weight function.

 

Question

Why is the weight function included? Can the orthogonality of the associated Laguerre polynomials be defined as , where ? Why are the limits of integration from 0 to ? Why are the polynomials and not ?

Answer

The weight function is an integral part of the orthogonality definition of associated Laguerre polynomials due to its role in ensuring convergence and its practical applications. It is often tied to specific problems, such as those in quantum mechanics. Omitting the weight function would sever this connection and could potentially alter the orthogonality properties of the polynomials. Therefore, defining orthogonality without the weight function would generally be invalid and would not reflect the intended use and properties of the associated Laguerre polynomials.

The weight function naturally defines the integration range because as , making the integral convergent over this range. This range is also connected to specific problems, such as the radial part of the wave functions in quantum mechanics. In the context of the hydrogen atom, represents a distance, which is always non-negative.

The eigenvalue of is a function of and not . Since the eigenfunctions of a Hermitian operator are orthogonal, two associated Laguerre polynomials with distinct values of  must be orthogonal. If we allow the values of to be different, we wouldn’t know if the result of the integral is solely due to the values of .

 

To prove eq453, we multiply the generating function for the associated Laguerre polynomials (see eq448) for and to give

Multiplying through by and integrating with respect to yields

 

Question

Show that , where is a non-negative integer.,

Answer

Let , and , and then and . Integrating by parts,

Let and , and then and . Integrating by parts

If we carry out integrations by parts, we have

 

Therefore, eq454 becomes

Expressing the LHS as a binomial series,

So,

Equating the coefficients of when  gives eq453.

 

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