X-ray crystallography: hexagonal and rhombohedral

The simplest way to form a three-dimensional Bravais lattice with 6-fold rotational symmetry is to stack the lattices of figure V one above another (Va), giving the primitive hexagonal unit cell (demarcated by red lines in Vb) with IaI = IbI ≠ Icand α = β = 90oγ = 120o.

A three-dimensional Bravais lattice with 3-fold rotational symmetry is formed by a staggered stacking of layers of figure V, with equal separation distance between layers. The lateral position of the second layer is such that the lattice points of this layer are above the middle of equilateral triangles formed by the first layer (Vc). The third layer is also staggered in the similar way with its lattice points above the middle of equilateral triangles formed by the first as well as the second layer. This is known as the triple hexagonal lattice.

If we continue this manner of staggered-stacking, we have the lattice points of fourth layer lying directly above those of the first layer, giving an XYZXYZ stacking arrangement and producing the primitive rhombohedral unit cell (Vd) with IaI = IbI = Icand α = β = γ ≠ 90o.

Note that the triple hexagonal lattice (Vc) does not have any 6-fold rotational symmetry, since a rotation of 600 using an axis perpendicular to the plane of the page and through the red lattice point maps lattice point 1 of the second layer to lattice point 2 of the third layer and not to lattice point 3.

 

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X-ray crystallography: cubic

There are 3 types of cubic unit cells: primitive, body-centred and face-centred.

A three-dimensional Bravais lattice with 4-fold rotational symmetry is created by stacking figure IV lattices one above another (IVa), resulting in the primitive cubic unit cell (IVb) with IaI = IbI = Icand α = β = γ = 90o.

If we stagger the second layer so that the lattice points are in the middle of squares formed by the first layer (IVc), followed by a third layer that is directly above the first layer, we have the non-primitive body-centred cubic unit cell (IVd) with IaI = IbI = Icand α = β = γ = 90o.

The primitive cubic unit cell can also be formed via the triple hexagonal lattices of Vc when the perpendicular distance between two layer of lattices is (IaI√6)/6 (see next article for proof). Similarly, the face-centred cubic unit cell (IVe) with IaI = IbI = Icand α = β = γ = 90o, is created via the triple hexagonal lattices of Vc when the perpendicular distance between two layer of lattices is (IaI√6)/3 (see next article for proof).

Even though it is possible to demarcate three-dimensional primitive rhombohedral unit cells for the body-centred cubic and face-centred cubic lattices, the primitive cells are not used to represent the two lattices as they do not reveal the higher rotational symmetry of the cubic lattices and are hard to visualise with their inter-axial angles not at 900.

 

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